Es and Derivatives: Application of Uncomplicated and Extended Types from the Grunwald-Winstein Equations. Cur. Org. Chem. 2012; 16:1502?511. 47. Kevill DN, Koyoshi F, D’Souza MJ. Correlation from the Precise Rates of Solvolysis of Aromatic Carbamoyl Chlorides, Chloroformates, Chlorothionoformates, and Chlorodithioformates Revisited. Int. J. Mol. Sci. 2007; 8:346?52. 48. Kevill DN, D’Souza MJ. Correlation in the Rates of Solvolysis of Phenyl Chlorothionoformate and Phenyl Chlorodithioformate. Can. J. Chem. 1999; 77:1118?122. 49. He X-S, Brossi A. Di-(two,2,2-Trichloroethyl)-Carbonate: Byproduct in Reactions with 2,2,2Trichloroethyl Chloroformate. Syn. Commun. 1990; 20:2177?179. 50. Olofson RA. New, Useful Reactions of Novel Haloformates and Associated Reagents. Pure Appl. Chem. 1998; 60:1715?724. 51. Yamamoto K, Takemae M. The Utility of t-Butyldimethylsilane as an efficient Silylation Reagent for the Protection of Functional Groups. Bull. Chem. Soc. Japan. 1989; 62:2111?113. 52. Sandosky, B.; D’Souza, MJ.; Kevill, DN. Abstracts of Papers of your American Chemical Society (Vol. 241). Vol. 1155. 16th ST, NW, Washington, DC 20036 USA: 2011 Mar. Correlation of theNIH-PA Author PPARĪ³ site Manuscript NIH-PA Author Manuscript NIH-PA Author ManuscriptCan Chem Trans. Author manuscript; obtainable in PMC 2014 May well 06.D’Souza et al.PageRates of Solvolysis of two,two,2-Trichloro-1,1,-Dimethylethyl Chloroformate. Abstract #833, Division of Chemical Education (CHED). 53. Kevill DN, D’Souza MJ. Correlation of the Rates of Solvolysis of n-Octyl Fluoroformate in addition to a Comparison with n-Octyl Chloroformate Solvolysis. J. Chem. Soc. Perkin Trans 2. 2002; two:240?243. 54. Byers JA, Jamison TF. Entropic Variables Offer Uncommon Reactivity and Selectivity in EpoxideOpening Reactions Promoted by Water. Proc. Nat. Acad. Sci. 2013; 110:16724?6729. [PubMed: 24046369]NIH-PA Author Manuscript NIH-PA Author Manuscript NIH-PA Author ManuscriptCan Chem Trans. Author manuscript; out there in PMC 2014 Could 06.D’Souza et al.Trk Formulation PageNIH-PA Author Manuscript NIH-PA Author Manuscript NIH-PA Author ManuscriptFigure 1.Molecular structures of phenyl chloroformate (1), phenyl chlorodithioformate (two), 2,2,2trichloro-1,1-dimethylethyl chloroformate (3), two,2,2-trichloroethyl chloroformate (four), and 1chloroethyl chloroformate (five)Can Chem Trans. Author manuscript; available in PMC 2014 Might 06.D’Souza et al.PageNIH-PA Author Manuscript NIH-PA Author ManuscriptFigure two.The plot of log (k/ko)3 against log (k/ko)PhOCOClNIH-PA Author ManuscriptCan Chem Trans. Author manuscript; obtainable in PMC 2014 May 06.D’Souza et al.PageNIH-PA Author Manuscript NIH-PA Author ManuscriptFigure three.The plot of log (k/ko) for two,2,2-trichloro-1,1-dimethylethyl chlorothioformate (three) against 1.43 NT + 0.38 YCl in nineteen pure and binary solvents. The 97 HFIP point was not included inside the correlation. It really is added to the plot to show the extent of its deviationNIH-PA Author ManuscriptCan Chem Trans. Author manuscript; obtainable in PMC 2014 May 06.D’Souza et al.PageNIH-PA Author Manuscript NIH-PA Author ManuscriptFigure 4.The plot of log (k/ko)4 against log (k/ko)PhOCOClNIH-PA Author ManuscriptCan Chem Trans. Author manuscript; obtainable in PMC 2014 May possibly 06.D’Souza et al.PageNIH-PA Author Manuscript NIH-PA Author Manuscript NIH-PA Author ManuscriptCan Chem Trans. Author manuscript; out there in PMC 2014 Might 06.Figure 5.The plot of log (k/ko)5 against log (k/ko)PhOCOClD’Souza et al.PageNIH-PA Author ManuscriptScheme 1.A carbonyl addition method for chlo.
